Alkyl monolayers on silica surfaces prepared using neat, heated dimethylmonochlorosilanes with low vapor pressures

Ghaleb A. Husseini; Justin Peacock; Amarchand Sathyapalan; Lloyd W. Zilch; Matthew C. Asplund; Eric T. Sevy; Matthew R. Linford

doi:10.1021/la020986l

Alkyl monolayers on silica surfaces prepared using neat, heated dimethylmonochlorosilanes with low vapor pressures

Ghaleb A. Husseini^*, Justin Peacock, Amarchand Sathyapalan, Lloyd W. Zilch, Matthew C. Asplund, Eric T. Sevy, Matthew R. Linford

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A rapid, facile, and reproducible preparation of monolayers on silicon oxide surfaces using neat, heated dimethylmonofunctional silanes is presented. In the case of a solid silane, enough material is placed on the surface so that upon heating its melt completely covers the surface. The surface and silane are heated for 10 min in an oven at 60-120°C. Excess reagent is finally removed, and the surfaces are characterized with X-ray photoelectron spectroscopy, spectroscopic ellipsometry, and wetting.

Original language	English
Pages (from-to)	5169-5171
Number of pages	3
Journal	Langmuir
Volume	19
Issue number	12
DOIs	https://doi.org/10.1021/la020986l
State	Published - 10 Jun 2003
Externally published	Yes

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10.1021/la020986l

Cite this

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title = "Alkyl monolayers on silica surfaces prepared using neat, heated dimethylmonochlorosilanes with low vapor pressures",

abstract = "A rapid, facile, and reproducible preparation of monolayers on silicon oxide surfaces using neat, heated dimethylmonofunctional silanes is presented. In the case of a solid silane, enough material is placed on the surface so that upon heating its melt completely covers the surface. The surface and silane are heated for 10 min in an oven at 60-120°C. Excess reagent is finally removed, and the surfaces are characterized with X-ray photoelectron spectroscopy, spectroscopic ellipsometry, and wetting.",

author = "Husseini, {Ghaleb A.} and Justin Peacock and Amarchand Sathyapalan and Zilch, {Lloyd W.} and Asplund, {Matthew C.} and Sevy, {Eric T.} and Linford, {Matthew R.}",

year = "2003",

month = jun,

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doi = "10.1021/la020986l",

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T1 - Alkyl monolayers on silica surfaces prepared using neat, heated dimethylmonochlorosilanes with low vapor pressures

AU - Husseini, Ghaleb A.

AU - Peacock, Justin

AU - Sathyapalan, Amarchand

AU - Zilch, Lloyd W.

AU - Asplund, Matthew C.

AU - Sevy, Eric T.

AU - Linford, Matthew R.

PY - 2003/6/10

Y1 - 2003/6/10

N2 - A rapid, facile, and reproducible preparation of monolayers on silicon oxide surfaces using neat, heated dimethylmonofunctional silanes is presented. In the case of a solid silane, enough material is placed on the surface so that upon heating its melt completely covers the surface. The surface and silane are heated for 10 min in an oven at 60-120°C. Excess reagent is finally removed, and the surfaces are characterized with X-ray photoelectron spectroscopy, spectroscopic ellipsometry, and wetting.

AB - A rapid, facile, and reproducible preparation of monolayers on silicon oxide surfaces using neat, heated dimethylmonofunctional silanes is presented. In the case of a solid silane, enough material is placed on the surface so that upon heating its melt completely covers the surface. The surface and silane are heated for 10 min in an oven at 60-120°C. Excess reagent is finally removed, and the surfaces are characterized with X-ray photoelectron spectroscopy, spectroscopic ellipsometry, and wetting.

UR - http://www.scopus.com/inward/record.url?scp=0038274594&partnerID=8YFLogxK

U2 - 10.1021/la020986l

DO - 10.1021/la020986l

M3 - Article

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